Cyclovibsanins, Unprecedented Seven-Membered Vibsane-Type Diterpenes from Viburnum awabuki

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Four unprecedented vibsane-type diterpenes, named cyclovibsanin A, 15-Omethylcyclovibsanin A, 15-O-methylcyclovibsanin B, and 3-hydroxy-15-O-methylcyclovibsanin A, were isolated from the leaves of Viburnum awabuki. Their unique tricyclo[,0]tridecane structures and plausible biosynthesis of cyclovibsanins are discussed here.

Keywords: cyclovibsanin; seven-membered vibsane; vibsane-type diterpene; viburnum awabuki

Document Type: Review Article


Affiliations: Institute of Pharmacognosy, Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Tokushima 770-8514, Japan.

Publication date: April 1, 2004

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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