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Aminophosphanes as Iminophosphoranyl Synthons: Efficient P-H Addition to Activated C=C Bonds

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Abstract:

Asymmetrically substituted bis(iminophosphoranes) derived from 1,2- bis(diphenylphosphino)ethane are prepared by Michael-type addition of easily available N,P,P-trisubstituted aminophosphanes to P-vinyl iminophosphoranes. Similarly P-alkylations of aminophosphanes with P-vinyl phosphane oxides and sulfides are also disclosed.

Keywords: aminophosphanes; iminophosphoranes; michael addition; phosphorus

Document Type: Review Article

DOI: http://dx.doi.org/10.2174/1570178043488356

Affiliations: Departamento de Química Organica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30100 Murcia, Spain.

Publication date: April 1, 2004

More about this publication?
  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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