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Aminophosphanes as Iminophosphoranyl Synthons: Efficient P-H Addition to Activated C=C Bonds

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Asymmetrically substituted bis(iminophosphoranes) derived from 1,2- bis(diphenylphosphino)ethane are prepared by Michael-type addition of easily available N,P,P-trisubstituted aminophosphanes to P-vinyl iminophosphoranes. Similarly P-alkylations of aminophosphanes with P-vinyl phosphane oxides and sulfides are also disclosed.
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Keywords: aminophosphanes; iminophosphoranes; michael addition; phosphorus

Document Type: Review Article

Affiliations: Departamento de Química Organica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30100 Murcia, Spain.

Publication date: 2004-04-01

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