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Synthesis and Stability of 1-Phenylethenyl Phosphate Derivatives and their Phosphoryl Transfer Activity

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Abstract:

1-Phenylethenyl phosphate derivatives of the monoester type were synthesized via the Perkow reaction. Among them, 2-(2,4-difluorophenyl)ethenyl phosphate was found to be obtained as a pure salt. It turned out that this compound and 2-phenylethenyl phosphate can transfer their phosphoryl groups to AMP in pyridine at elevated temperatures to give ADP.

Keywords: enol phosphate; perkow reaction; phosphoryl transfer; phosphorylation

Document Type: Review Article

DOI: https://doi.org/10.2174/1570178043488482

Affiliations: CREST, JST (Japan Science and Technology Agency) Nagatsuta, Midori-ku, Yokohama 226-8501, Japan.

Publication date: 2004-04-01

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