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Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines having Electron-Withdrawing Substituents

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As a new direct functionalization of guanidines, the N-allylic substitution of guanidines was studied. The nitrogen atom of guanidine derivatives having two Nelectron- withdrawing substituents acted as a reactive nucleophile in the allylic substitution.

Keywords: allylation; allylic substitution; catalytic reaction; guanidine; iridium; palladium

Document Type: Review Article


Affiliations: Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.

Publication date: April 1, 2004

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.

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