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Nucleophilic Additions of Niobium Enolates of Oxazolidinones to Aromatic Aldehydes and Aldimines

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Abstract:

Niobium enolate of oxazolidinone 2 was generated by the combination of NbCl5 and a tertiary amine, which then reacted with benzaldehyde and aldimines. The products were obtained in good yields.

Keywords: niobium enolate; niobium pentachloride; nucleophilic additions; oxazolidinones

Document Type: Review Article

DOI: http://dx.doi.org/10.2174/1570178043488491

Affiliations: Laboratorio de Quimica Metodologica e Organica Sintetica (LaQMOS), Instituto de Quimica, Universidade de Brasília, C.P. 4478, 70910-970, Brasilia, DF, Brazil.

Publication date: April 1, 2004

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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