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Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates

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A Barbier-type allylation of aldimines by allylic acetates in the presence of zinc dust and a simple cobalt halide catalyst takes place in acetonitrile to give the corresponding homoallylic amines in good yields.
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Keywords: allylation; cobalt halide; homo-allylic amines; imines

Document Type: Review Article

Affiliations: Laboratoire d’Electrochimie, Catalyse et Synthese Organique, UMR 7582, Universite Paris 12 – C.N.R.S, 2, Rue Henri Dunant, F-94320 THIAIS, France.

Publication date: 2004-04-01

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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