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Advances in Ruthenium Catalysis. Novel Catalytic Reactions via η3- Allylruthenium Intermediates

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Abstract:

Recent developments in ruthenium-catalyzed chemo-, regio-, and stereoselective C-C bond forming reactions as well as a C-C bond cleaving reaction via an η3-allylruthenium intermediate are disclosed, in which novel ambiphilic reactivity of η3-allylruthenium complexes is discussed. In addition, a new route to cyclopentenones via ruthenium-catalyzed carbonylative cyclization of allylic carbonates with alkenes, which would be the complement of the catalytic intermolecular Pauson-Khand reaction, is also presented.

Keywords: allylruthenium complexe; allylruthenium intermediates; chemoselective reactions; pauson-khand reaction; regioselective reactions; ruthenium catalysis

Document Type: Review Article

DOI: https://doi.org/10.2174/1385272023373545

Publication date: 2002-11-01

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