Spectroelectrochemical Characterization of Organic and Metal-Organic Compounds

Authors: Toma H.E.; Araki K.

Source: Current Organic Chemistry, Volume 6, Number 1, January 2002 , pp. 21-34(14)

Publisher: Bentham Science Publishers

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Abstract:

This account focuses on the application of uv-vis and ir spectroelectrochemistry in the characterization of organic and related metal-organic molecules, from the point of view of their electrochemical and redox properties. Special emphasis has been given to the elucidation of multiple or successive redox processes. The scope has been limited to systems such as porphyrins, iron-amines, macrocycles and supramolecular porphyrins, spanning the last 15 years not covered by previous review articles on the subject.

Keywords: Spectroelectrochemical Characterization; Metal-Organic Compounds; spectroelectrochemistry; hypsochromic shift; Electrocarboxylation; metal-induced dehydrogenation

Language: English

Document Type: Review article

DOI: 10.2174/1385272023374607

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