Synthesis of Heterocycles via Intramolecular Annulation of Nitrene Intermediates

Author: Soderberg B.C.G.

Source: Current Organic Chemistry, Volume 4, Number 7, July 2000 , pp. 727-764(38)

Publisher: Bentham Science Publishers

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Abstract:

This article presents a comprehensive review of synthetically useful intramolecular annulation reactions of nitrene and nitrenoid intermediates leading to heterocyclic compounds. Thermal, photochemical, and metal mediated reactions of aryl- and vinylazides, azirines, nitroso, and nitro compounds leading to synthetically useful yields of heterocycles are discussed.

Keywords: Intramolecular annulation; Nitrene intermediates; ARYL; Heteroaryl azides; Vinylazides; Azirines; Aromatic nitro compounds; Metal mediated reactions

Language: English

Document Type: Review article

DOI: 10.2174/1385272003376067

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