Self-Assembled Superlattices from Colloidal TiO2 Nanorods

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Abstract:

The self-assembly of anatase TiO2 nanorods into 1D (ribbon), 2D (smectic, domino, honeycomb) and 3D (lamellar) liquidcrystalline ordered superlattices is a process that depends on the collaboration between evaporation dynamics and directional interactions. Herein, the roles of entropic depletion attractions and energetic dipole-dipole couplings between TiO2 nanorods in self-assembly process are particularly emphasized. Excess oleic acid surfactants act as depletion agents to induce the inter-rod depletion effect, and the origin of electric dipole moment along the longitudinal axes of TiO2 rods is theoretically authenticated by applying the Accelrys Materials Studio as a new strategy combined with Tasker's theory. These nanorod superlattices provided here may have great importance for tailoring new promising structures for photovoltaic application or exploring new inorganic liquid crystal materials.





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  • Current Nanoscience publishes authoritative reviews and original research reports, written by experts in the field on all the most recent advances in nanoscience and nanotechnology. All aspects of the field are represented including nano- structures, synthesis, properties, assembly and devices. Applications of nanoscience in biotechnology, medicine, pharmaceuticals, physics, material science and electronics are also covered. The journal is essential to all involved in nanoscience and its applied areas.
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