A Model of Single Molecule Magnet Behaviour of 3d-4f Clusters
We report a model for the explanation of the single molecule magnet behavior of the [CuIILTbIII (hfac)2]2 cluster. The model takes into account the crystal field acting on the TbIII ion and the exchange interaction between TbIII and CuII ions. The energies of the low-lying levels are shown to increase with the decrease of the mean value of the Z-projection of the total angular momentum of the cluster, thus forming a barrier for magnetization reversal that is in accordance with the experimental evidence.
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Document Type: Research Article
Publication date: 2009-04-01
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- Journal of Nanoelectronics and Optoelectronics (JNO) is an international and cross-disciplinary peer reviewed journal to consolidate emerging experimental and theoretical research activities in the areas of nanoscale electronic and optoelectronic materials and devices into a single and unique reference source. JNO aims to facilitate the dissemination of interdisciplinary research results in the inter-related and converging fields of nanoelectronics and optoelectronics.
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