Tio2 Paste Formulation for Crack-Free Mesoporous Nanocrystalline Film of Dye-Sensitized Solar Cells
Authors: Sarker, Subrata; Nath, Narayan Chandra Deb; Rahman, Md. Mahbubur; Lim, Sung-Su; Ahammad, A. J. Saleh; Choi, Won-Youl; Lee, Jae-Joon
Source: Journal of Nanoscience and Nanotechnology, Volume 12, Number 7, July 2012 , pp. 5361-5366(6)
Publisher: American Scientific Publishers
Abstract:Using a doctor-blade method, a highly viscous titanium dioxide (Tio2) paste was deposited on a glass substrate coated with fluorine doped tin oxide (FTO). The paste was mainly composed of commercially available Tio2 nanoparticles (P25) and hydroxypropyl cellulose (HPC) as organic filler. Varying the content of HPC in the Tio2 paste changed the physical properties of the mesoporous Tio2 layer, particularly its porosity and surface area. From the quantification of dyes on Tio2 layer and the electrochemical impedance spectroscopy (EIS) study of the dye-sensitized solar cells (DSSCs), the surface area of the Tio2 film was found to have decreased. This came with the increase of HPC content while the porosity of the film increased, consistent with the concurrent decrease of short-circuit current density (J sc) and efficiency (μ). The increased porosity greatly affected the electron transport through the Tio2 film by decreasing the coordination number of the Tio2 particles resulting to a decrease of the electron diffusion coefficient.
Document Type: Research Article
Publication date: 2012-07-01
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Terms & Conditions
- ingentaconnect is not responsible for the content or availability of external websites