Synthesis and Characterization of Multifunctional Periodic Mesoporous Organosilica from Diureidophenylene Bridged Organosilica Precursor

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Abstract:

This paper reports the periodic mesoporous organosilicas (PMOs) functionalised with newly synthesized bis-silylated (1,1(1,4-phenylene (bis-3-(3-triethoxysilylpropyl)urea)(BSBDA)) organosilica with 1,2-bis(triethoxysilyl) ethane (BTSE) using a co-condensation process. X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), nitrogen adsorption–desorption, NMR (proton, 13C and 29Si) spectra, and MALDI-TOF were used to characterise and evaluate the structural properties. The results showed that BSBDA is linked covalently to the mesochannel of the PMO frameworks. The pore size and overall structural properties in the functionalised PMOs were found to depend on the loading amounts of BSBDA. The overall results suggested that the highly functionalised PMOs could be tuned even at high BSBDA loadings (25 wt%).

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2012.6215

Publication date: June 1, 2012

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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