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Analysis of the Electron Transport Properties in Dye-Sensitized Solar Cells Using Highly Ordered TiO2 Nanotubes and TiO2 Nanoparticles

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This study uses TiO2 nanoparticles and highly ordered anatase TiO2 nanotubes (AOTnt) as thin film photoanodes for dye-sensitized solar cells (DSSCs). DSSCs are assembled by single-layer and double-layer films of photoanodes and their electron transfer performance is compared. TiO2 nanoparticles were fabricated by the sol–gel method, and AOTnts were grown on titanium foil. This study uses TiO2 nanoparticles or AOTnts to prepare single-layer photoanodes and TiO2 nanoparticles coated on an AOTnt film to fabricate double-layer photoanodes. These three different photoanodes are soaked in dye and assembled into DSSCs, and their open-loop voltage recession, electrochemical impedance, lifetime, life cycle, and effective diffusion coefficient are measured. Electron transfer efficiency of the photoanodes and light harvesting efficiency are further analyzed. The results show that the electron transfer efficiency, open-loop voltage recession, lifetime, life cycle, and effective diffusion coefficient of the DSSCs assembled using double-layer photoanodes (AOTnt-TiO2) are superior to those of single-layer photoanodes (TiO2 or AOTnt).
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Document Type: Research Article

Publication date: 2012-04-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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