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Hydrothermal Synthesis of ZnO Nanorods in the Presence of a Surfactant

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Abstract:

Controlling the dimensions, positioning, and shapes of semiconductor nanowires, nanorods, and nanobelts lies in the synthesis and understanding of their growth mechanism. Controlled growth and synthesis is required in the fabrication of nanodevices and nanosensors. Among methods utilized for one-dimensional nanostructure synthesis, the hydrothermal process—a simple and cost-effective technique involving a low process temperature—has emerged as a powerful tool for the fabrication of anisotropic nanomaterials. Under hydrothermal conditions, many starting materials can undergo quite unexpected reactions, which are often accompanied by the formation of nanoscopic morphologies that are not accessible by classical routes. Synthesized ZnO nanostructures from aqueous solutions are usually poor in terms of morphology and size control. To improve the growth conditions and the controllability of the process, the use of surfactants or organic solvents has been attempted. In the present work, ZnO nanorods were grown on templates with a pre-sputtered ZnO seed layer over oxidized Si (100) substrates, and polyvinyl pyrrolidone (PVP) was used as a surfactant. By varying the PVP concentration in the growth solution, we can control the diameter and density of ZnO nanorods. The optical property of ZnO nanorods is highly improved by PVP addition.

Keywords: HYDROTHERMAL; NANORODS; SURFACTANT; ZINC OXIDE

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2012.4652

Publication date: 2012-02-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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