Mechanism Behind the Formation of Self-Assembled Nano-Sized Clusters in Diamond-Like Carbon Nanocomposite
Abstract:Many studies have shown that Diamond-like carbon (DLC) films with diversified material properties are obtainable through doping process but the presence of the dopants were reported to form independent nanoclusters within the carbon matrix. Using combined analysis from theoretical estimations (Saha's equation and coefficient of absorption, α p ), Transport of Ions In Matter (TRIM) simulation and experimental results, this work examined the mechanism behind the formation of self-assembled nanoclusters in DLC nanocomposite. We showed that the presence of metal dopants increased the heat dissipation on DLC, which allowed the energetic metal species to diffuse and enhance the formation of nanoclusters that increased the surface roughness of the films. In addition, TRIM and X-ray Photoelectron Spectroscopy (XPS) hinted the presence of energetic species may force the carbon ions to react with the interface to form silicon carbide bonds, which may be a more dominant factor compared to internal stress reduction in improving the adhesion strength of DLC.
Document Type: Research Article
Publication date: 2011-12-01
More about this publication?
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Terms & Conditions
- Ingenta Connect is not responsible for the content or availability of external websites