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Preparation, Characterization, and Photoelectric Properties of a Covalently Self-Assembled Monolayer of Ferrocenyl Hemicyanine

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A monolayer of a ferrocenyl hemicyanine was covalently self-assembled on an indium tin oxide (ITO)-coated glass substrate, and was characterized by UV/Vis absorption and X-ray photoelectron spectroscopy, and cyclic voltammetry. The photoelectrochemical properties and mechanism of photocurrent generation have also been studied. This monolayer film was found to exhibit a large anodic photocurrent density of 0.13 μA/cm2 with the highest photoelectric yield of 3.32% under irradiation of white light (730 nm > λ > 325 nm) at a bias potential of +0.4 V versus saturated calomel electrode.
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Keywords: FERROCENE; HEMICYANINE; PHOTOELECTRIC PROPERTY; SELF-ASSEMBLED FILM

Document Type: Research Article

Publication date: 2011-11-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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