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Preparation and Photocatalytic Activity of an Electrostatically Self-Assembled Film Made of [PMo12O40]3− and a Bipolar Hemicyanine Cation

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An electrostatically self-assembled film of PMo12/H6 has successfully been prepared on quartz substrates by alternating adsorption of [PMo12O40]3− (PMo12) and a bipolar hemicyanine derivative of (E)-1,1′-(hexane-1,6-diyl)bis(4-(4-(dimethylamino)styryl)pyridinium) bromide (H6Br2). The UV-visible spectra showed that the film was uniformly deposited and the charge transfer between two filmforming components might occur in the film. The photocatalytic performance of the film was studied for the degradation of aqueous dye Methyl Red (MR) under UV irradiation. The degradation of MR follows Langmuir-Hinshelwood first-order kinetics.
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Document Type: Research Article

Publication date: 2011-11-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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