Metal Ion Detection with Oligo(ethylene glycol) Monolayer-Modified Gold Nanoparticles
Authors: Li, Guangzhao; Yang, Bin; Lu, Zhiqiang; Xia, Sijing; Feng, Hui; Zhu, Xiaoqing; Wang, Anning; Zhu, Jin
Source: Journal of Nanoscience and Nanotechnology, Volume 11, Number 11, November 2011 , pp. 9469-9477(9)
Publisher: American Scientific Publishers
Abstract:Two colorimetric sensors of gold nanoparticles (AuNPs) modified with different oligo(ethylene glycol)-containing organic molecules have been developed to detect metal ions by ultraviolet-visible (UV-vis) extinction spectroscopy. These sensors display different responses to some metal ions. One exhibits high selectivity for Hg2+ over a variety of competitive metal ions and the other one can respond to a multitude of metal ions. These differences might result from the different functionalized end groups of the modified molecules. Coordination effect, pH response, and ionic strength were investigated to understand the mechanism of the responses to metal ions. The results suggested that the colorimetric responses were mainly induced by the coordination effect of the modified organic molecules and the removing of the modified organic molecules caused by metal ions.
Document Type: Research Article
Publication date: November 1, 2011
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