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Electronic Structure and Magnetic Properties of a Molecular Octanuclear Chromium-Based Ring

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Abstract:

A comprehensive study of electronic and magnetic properties of Cr8F8Piv16 (HPiv = pivalic acid, trimethyl acetic acid) molecular ring is presented. The total, local and orbital projected density of states are calculated by the first principle density functional theory calculations using the package SIESTA. The original molecule has been approximated by replacing the pivallic groups by H atoms (hydrogen saturation). Electron density, deformation density, electrostatic potential and spin density maps are analyzed and compared with experiment for the first time. Magnetic properties are investigated in detail. Magnetic moments are calculated using two different approaches: the Mulliken one and integration of muffin-tin sphere with a given radius. Different magnetic configurations (ferromagnetic, antiferromagnetic and many more with randomly distributed spins up and down) are considered to extract exchange interaction parameter J and check the stability of its estimate.

Keywords: CHROMIUM; DFT CALCULATIONS; HETEROMETALLIC WHEELS; MOLECULAR MAGNETS

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2011.4300

Publication date: 2011-10-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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