Study on Adsorption of Co(II) and Ni(II) onto Mesoporous Ti-Containing MCM-48
Authors: Chen, Jinjin; Fang, Keming; Miao, Yuqing; Qian, Zhaosheng; Chen, Jianrong
Source: Journal of Nanoscience and Nanotechnology, Volume 11, Number 8, August 2011 , pp. 6796-6803(8)
Publisher: American Scientific Publishers
Abstract:Ti-containing MCM-48 (Ti-MCM-48) material with mesoporous structure was synthesized and characterized, and the absorption processes of Co(II) and Ni(II) on the material were investigated in detail in the present study. The Ti- MCM-48 was synthesized by hydrothermal reaction and characterized by XRD, FT-IR and nitrogen sorption methods. Optimum pH value for maximum adsorption rate is 8.0, and the saturated adsorption capacities of Ti-MCM-48 for Co(II) and Ni(II) are 9.870 and 22.94 mg·g−1 respectively, which are greater than those of the reported materials Adsorption isotherms of Co(II) and Ni(II) on Ti-MCM-48 accord well with the Langmuir adsorption models. Kinetic data of adsorption reactions and the adsorption equilibrium parameters were also determined, and the obtained data correlated linearly with the pseudo-second order equation.
Document Type: Research Article
Publication date: August 1, 2011
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