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New Deep Blue Emitting Materials Based on Indenopyrazine Core with High Thermal Stability

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Abstract:

New deep blue emitting materials 2,8-bis(3,5-diphenylphenyl)-6,6,12,12-tetraethyl-6,12-dihydrodiindeno[1,2-b:1′,2′-e]pyrazine (DPP-EPY) and 2,8-bis(3′,5′-diphenylbiphenyl-4-yl)-6,6,12,12-tetraethyl-6,12-dihydrodiindeno[1,2-b:1′,2′-e]pyrazine (DPBP-EPY) were synthesized through introduction of m-terphenyl or triphenylbenzene bulky side groups in a new indenopyrazine core. These materials all showed high thermal stability and highly reduced intermolecular interaction. DPP-EPY and DPBP-EPY showed PL maxima of 456 nm and 460 nm in deep blue region and narrow PL spectra with full-width at half-maximum (FWHM) of 46 nm and 52 nm, respectively. As a result of making non-doped OLED devices using these synthesized materials as emitting layers, DPP-EPY showed EL spectrum of 452 nm, very narrow FWHM of 46 nm, luminance efficiency of 1.04 cd/A with current density of 10 mA/cm2 and CIE coordinate of (0.161, 0.104), creating a deep blue OLED close to the National Television System Committee (NTSC) blue standard.

Keywords: BLUE EMITTING MATERIAL; FLUORESCENCE; INDENOPYRAZINE; OLED

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2011.3693

Publication date: May 1, 2011

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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