@article {Gal:2011:1533-4880:4611, title = "Synthesis and Properties of Poly(4-vinylpyridine-co-styrene) with Pendant Azobenzonitrile Moieties", journal = "Journal of Nanoscience and Nanotechnology", parent_itemid = "infobike://asp/jnn", publishercode ="asp", year = "2011", volume = "11", number = "5", publication date ="2011-05-01T00:00:00", pages = "4611-4614", itemtype = "ARTICLE", issn = "1533-4880", eissn = "1533-4899", url = "https://www.ingentaconnect.com/content/asp/jnn/2011/00000011/00000005/art00146", doi = "doi:10.1166/jnn.2011.3677", keyword = "AZOBENZONITRILE, POLY(4-VINYLPYRIDINE-CO-STYRENE), CYCLIC VOLTAMMOGRAM, POLYMER REACTION, OPTICAL PROPERTIES", author = "Gal, Yeong-Soon and Lee, Won-Chul and Jin, Sung-Ho and Lyoo, Won Seok and Kim, Sung-Hoon and Park, Jong-Wook and Lim, Kwon Taek", abstract = "A new ionic polymer, poly(4-vinylpyridine-co-styrene) [PVPS] with pendant azobenzonitrile moieties was prepared by the polymeric reaction of PVPS and 4-[4-(8-bromooctyloxy)phenylazo]benzonitrile. The polymer structure was characterized by various instrumental methods to have a PVPS back-bone system with the designed azobenzonitrile moieties. The electrochemical and electro-optical properties were studied. The polymer showed two oxidation and reduction response properties in a polymer unit and two electrochemical processes were included in the irreversible redox steps. The plot of the oxidation current density of polymer versus the scan rate showed approximately a linear relationship in the range of 30 mV/sec150 mV/sec. The exponent of scan rate, when we apply power law to our data, was found to be 0.35. The absorption spectrum showed a characteristic absorption peak at 365 nm.", }