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Synthesis and Properties of Poly(4-vinylpyridine-co-styrene) with Pendant Azobenzonitrile Moieties

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Abstract:

A new ionic polymer, poly(4-vinylpyridine-co-styrene) [PVPS] with pendant azobenzonitrile moieties was prepared by the polymeric reaction of PVPS and 4-[4-(8-bromooctyloxy)phenylazo]benzonitrile. The polymer structure was characterized by various instrumental methods to have a PVPS back-bone system with the designed azobenzonitrile moieties. The electrochemical and electro-optical properties were studied. The polymer showed two oxidation and reduction response properties in a polymer unit and two electrochemical processes were included in the irreversible redox steps. The plot of the oxidation current density of polymer versus the scan rate showed approximately a linear relationship in the range of 30 mV/sec∼150 mV/sec. The exponent of scan rate, when we apply power law to our data, was found to be 0.35. The absorption spectrum showed a characteristic absorption peak at 365 nm.

Keywords: AZOBENZONITRILE; CYCLIC VOLTAMMOGRAM; OPTICAL PROPERTIES; POLY(4-VINYLPYRIDINE-CO-STYRENE); POLYMER REACTION

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2011.3677

Publication date: 2011-05-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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