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5-Isobutyryl-2-Phenylpyridine-Derived Iridium Complexes for Red Phosphorescent Light-Emitting Diodes

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For the development of efficient red materials in organic light emitting diodes, a series of cyclometalated iridium complexes with 5-isobutyryl-2-arylpyridine-derived ligands were synthesized. Complexes 1–4 exhibited red phosphorescence with quantum yields of 0.16–0.48 in degassed CH2Cl2. An OLED device employing iridium complex 3 as a dopant exhibited the best performance with a maximum luminance of 35500 cd/m2 at 14 V and luminance and power efficiencies of 15.5 cd/A and 6.23 lm/W at 20 mA/cm2, respectively. In the device employing complex 2 as the dopant, the maximum luminance was 6300 cd/m2 at 14 V and the maximum luminance efficiency and power efficiencies were 5.23 cd/A and 3.16 lm/W at 5.2 V, respectively, with CIE coordinates of (0.66, 0.32) at 9.0 V, close to the saturated red emission.
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Keywords: 5-ISOBUTYRYL-2-ARYLPYRIDINE LIGAND; ELECTROLUMINESCENCE; IRIDIUM COMPLEX; RED PHOSPHORESCENCE

Document Type: Research Article

Publication date: 2011-05-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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