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Luminescent Dye-Doped KAP Nanorods Obtained by Template Assisted Crystallization

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Abstract:

Luminescent nanorods of potassium acid phthalate (KAP) doped with rhodamine 6G (Rh 6G) dye molecules were grown by template assisted crystallization. Pores with diameters ranging from tens of nanometers to few micrometers were obtained in polycarbonate foils after heavy-ion irradiation and subsequent chemical etching of the damage trails along the ion trajectories. Crystallization from solution was employed for filling of the pores with the dye-doped KAP rods. These nanostructures were characterized using scanning electron microscopy, optical absorption spectroscopy and photoluminescence detection. X-ray diffraction was used for structural analysis. The luminescence of the dye-doped rods undergoes a redshift when the diameter of the structures decreases. This shift is probably caused by increasing dye concentration in the rods with decreasing pore diameter. The luminescence originating from the Rh 6G presence is up-converted due to the second-harmonic generation in KAP.

Keywords: DYE-DOPED; LUMINESCENCE; NANORODS; POTASSIUM ACID PHTHALATE; SOLUTION CRYSTALLIZATION; TEMPLATE SYNTHESIS; UP-CONVERSION

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2011.3832

Publication date: 2011-05-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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