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Microstructure and Magnetic Property of M-Type SrRExFe12−xO19 by Sol–Gel Method

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Magnetoplumbite-type (M-type) SrRExFe12−xO19 (RE = La and Ce, x = 0∼1.0) powders were prepared by a citric acid sol–gel technique and subsequent heat treatment. The crystal structure, grain size and magnetic properties were investigated by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM) and vibrating sample magnetometer (VSM). The XRD patterns show that SrRExFe12−xO19 (RE = La and Ce) are mainly hexagonal magnetic plumbite structure, and the average grain size of 30∼40 nm was calculated using the Scherer's equation based on the XRD spectrum. Substitution of Fe ion by the rare earth La ion causes a significant decrease in intrinsic coercivity (Hc) and a slight decrease in saturation magnetization (Ms) as shown in the magnetization hysteresis loops. However, the Hc rises gradually in a small wave pattern with the increase of doping content of the rare earth Ce. The relation between the crystal structure and magnetic properties was also studied in this work.
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Document Type: Research Article

Publication date: 2011-05-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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