Skip to main content

Synthesis and Characterization of Diiridium Complexes with a π-Conjugated Nanowire Chain

Buy Article:

$105.00 plus tax (Refund Policy)

The reaction of the iridium dimer [Ir(ppy)2(μ-Cl)]2 (ppy = 2-pyridiylphenyl) with bis(2,2′-bipyridin-5-yl) ethyne (bpy-C2-bpy), bis(2,2′-bipyridine)-butadiyne (bpy-C4-bpy), and bis (2,2′-bipyridin-5-yl-(Z)-hexa-3-ene-1,5-diyl) (bpy-C6H2-bpy) affords the following diiridium complexes: [ClO4]2 [(ppy)2Ir(bpy-C2-bpy)Ir(ppy)2] (1), [ClO4]2 [(ppy)2Ir(bpy-C4-bpy)Ir(ppy)2 (2), and [ClO4]2 [(ppy)2Ir(bpy-C6H2-bpy)Ir(ppy)2 (3), respectively. Herein, we describe the synthesis, characterization, and physical and electrochemical properties of the diiridium complexes in which the two iridium units are connected by a π-conjugated nanowire bridge.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Data/Media
No Metrics

Keywords: CONJUGATED CARBON BRIDGE; CYCLIC VOLTAMMOGRAM; IRIDIUM; PHENYLPYRIDINE; PHOTOLUMINESCENCE

Document Type: Research Article

Publication date: 2011-01-01

More about this publication?
  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Terms & Conditions
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more