Study on Luminescent Properties of Eu3+ Doped Gd2WO6, Gd2W2O9 and Gd2(WO4)3 Nanophosphors Prepared by Co-Precipitation
Authors: Meng, Qingyu; Hua, Ruinian; Chen, Baojiu; Tian, Yue; Lu, Shuchen; Sun, Linan
Source: Journal of Nanoscience and Nanotechnology, Volume 11, Number 1, January 2011 , pp. 182-188(7)
Publisher: American Scientific Publishers
Abstract:Eu3+ doped Gd2WO6Gd2W2O9 and Gd2(WO4)3 nanophosphors with different concentrations have been prepared by co-precipitation. XRD (X-ray diffraction) and SEM (scanning electron microscopy) were used to investigate the structure and morphology. The emission spectra, excitation spectra and fluorescence decay curves were measured, and partial J–O parameters and quantum efficiencies of Eu3+ 5D0 energy level were calculated. Furthermore, concentration quenching curves of Eu3+ in different hosts were drawn. The photoluminescent properties of Eu3+ doped Gd2WO6, Gd2W2O9 and Gd2(WO4)3 nanophosphors have been studied. The results indicate that Eu3+ 5D0–7F2 red luminescence can be effectively excited by 395 nm and 465 nm in Gd2WO6 and Gd2W2O9 hosts, similar to the familiar Gd2(WO4)3:Eu. Especially Gd2W2O9:Eu has strong red emission and high quenching concentration, so it has potential applications for trichromatic white LED as red fluorescent materials.
Document Type: Research Article
Publication date: 2011-01-01
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