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Assemblies of Fluorine Containing Bent-Shaped Liquid Crystal Molecules Studied by Using Scanning Tunneling Microscopy

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Abstract:

In this work we prepared a fluorine containing bent-shaped liquid crystal from biphenyl as the central core and rod-like azobenzene mesogens as the side arms, namely 4′,3-biphenyl bis[4-(4′-hexadecanloxy-3-fluorophenylazo)benzoate] (L104). The self-assembly behaviors of L104 molecules on graphite surface were investigated by using scanning tunneling microscopy (STM) under ambient conditions. The high-resolution STM images of L104 assemblies revealed three kinds of structures showing the joint effects of dipole–dipole interactions originated from the fluorine and the bent-core alignments for maximizing interactions. These observations may be beneficial for understanding the assembly mechanism and designs for novel banana-shaped liquid crystal molecules.

Keywords: BENT-SHAPED LIQUID CRYSTAL; SCANNING TUNNELING MICROSCOPE; SELF-ASSEMBLY

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2010.2835

Publication date: November 1, 2010

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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