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Synthesis and Characterization of AgI–Ag2O–SeO2 Glass-Nanocomposites Embedded with -AgI and Ag2SeO3 Nanocrystals

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Abstract:

Glass-nanocomposites of compositions xAgI − (1 − x)(0.40Ag2O–0.60SeO2) for 0.15 ≤ x ≤ 0.30 were prepared by quenching the melt of the appropriate mixtures of the chemicals AgI, AgNO3 and SeO2. Differential scanning calorimetry (DSC) was employed to determine the glass transition and crystallization temperatures. The as-prepared samples were heat-treated above glass transition temperature to observe the growth of nanoparticles. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) were used to explore the microstructure of these samples. These studies revealed the presence of -AgI and Ag2SeO3 nanocrystals in both the as-prepared and heat-treated samples. The particle size was found to decrease with the increase of AgI content in both cases. The heat-treated samples showed increased tendency of crystallization for the compositions with higher AgI content. The α phase transition of AgI crystals was observed at ∼147–149 °C for heat-treated samples. Fourier transform infrared (FTIR) spectra revealed that the basic structure of the glassy network remained invariant to change of AgI content as well as to heat-treatment.

Keywords: AG2SEO3 NANOCRYSTALS; BETA-AGI NANOPARTICLES; GLASS-NANOCOMPOSITES

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2010.2640

Publication date: 2010-10-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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