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Crack Formation During Post-Treatment of Nano- and Microfibres Prepared by Sol–Gel Technique

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We report on the method of TiO2 nano- and microfibres preparation and their cracking during processing and post-treatment. Nano- and microfibres were fabricated by drawing from viscous alkoxide based oligomeric concentrate precursors with the following exposure into an atmosphere of 30–50% humidity. The fibres microstructure was analyzed with TEM, solid state NMR, X-ray diffraction tools, and AFM. Experiments on crack formation in TiO2 microfibres proved that fibres with diameter larger than 10 micron are fractured for chosen post-treatment regimes. In theoretical considerations sol–gel produced and thermally treated microfibres are modeled as core/shell structures. It is suggested that the formation of fibres starts via solidification of liquid jet through the appearance of a rigid solid shell, which reveals tensile mechanical stresses because of material shrinkage. The effect of post-treatment is taken into account by additional densification of the fibre surface layer. The stress intensity factor KI is calculated for the model core/shell structures and the dependence of KI on the fibre diameter is demonstrated. The results of modeling qualitatively confirm experimental data of microfibre cracking above a certain threshold diameter.


Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2010.2562

Publication date: September 1, 2010

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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