Luminescence and Phonon Properties of Nanocrystalline Bi2WO6:Eu3+ Photocatalyst Prepared from Amorphous Precursor

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Abstract:

Bi2WO6:Eu3+ samples were prepared by mechanically activated metathesis reaction and subsequent annealing at different temperatures of the as-prepared precursor. X-ray, TEM, Raman, IR, diffuse reflectance and luminescence studies of the prepared samples are presented. It was found that variation of the particle size have significant impact on phonon and emission properties of this material. It was observed that intensity of some Raman and IR bands significantly decreases and the bandwidth of Raman, IR and Eu3+ emission lines significantly increases with decreasing particles size. Moreover, it was observed that intensity ratios I(5D07F2)/I(5D07F1) and I(5D07F0)/I(5D07F1) increase with decreasing particle size. The observed changes were attributed to phonon confinement effect, decrease in the orthorhombic distortion of the unit cell and concentration increase of surface defects.

Keywords: BI2WO6; BISMUTH LAYERED FERROELECTRICS; EU3+ LUMINESCENCE; NANOSIZED

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2010.2465

Publication date: September 1, 2010

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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