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Magnetic Properties of FexPtyAu100−xy Nanoparticles

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Abstract:

FexPtyAu100−xy nanoparticles of size 3.5 nm were prepared by polyol reduction of platinum acetylacetonate and gold acetate and the thermal decomposition of iron pentacarbonyl. The as-synthesized nanoparticles with disordered fcc structure were then heat treated to transform to the L10 structure with high magnetocrystalline anisotropy. By tuning the stoichiometry of the FexPtyAu100−xy nanoparticles, the phase transition temperature was reduced by more than 200 °C. After the annealing 500 °C, for instance, the highest coercivity of 18 kOe was obtained from the Fe51Pt36Au13 nanoparticles which is substantially higher compared to 2 kOe for Fe51Pt49 nanoparticles annealed at the same temperature. In addition to the high coercivity, the saturation magnetization value obtained from Fe51Pt36Au13 nanoparticles was 47 emu/g which is similar to that for the Fe51Pt49 nanoparticles, indicating that there is no trade-off between the coercivity and the saturation magnetization upon Au doping.

Keywords: BIOMEDICAL APPLICATIONS; CHEMICAL SYNTHESIS; DATA STORAGE; NANOPARTICLES; PERMANENT MAGNETS

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2010.2166

Publication date: May 1, 2010

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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