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From Single-Molecule Precursors to Hybrid ZnS Nanostructures

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Abstract:

A series of coordination compounds containing [Zn(amine)]2+ cationic complexes and alkyldithiocarbamates (RR′dtc), as counter anions, are reported here: [Zn(amine)x][RR′ dtc]2, where amine = ethylenediamine (en), diethylenetriamine (dien), 1,2-diaminopropane (dap) and, R,R′ = ethyl (Et); butyl (Bu) and methyl (Me), hexyl (Hex). Hybrid nanoplates composed of hexagonal-ZnS nanoparticles and organic components were obtained after solution phase thermolysis of such precursors in oleylamine. These hybrid materials show quantum confinement effects in their optical spectra and convert into cubic-ZnS after further thermal treatment.

Keywords: HYBRID MATERIALS; METAL DITHIOCARBAMATO COMPLEXES; NANOSTRUCTURES; ZINC SULFIDE

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2010.1403

Publication date: April 1, 2010

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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