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The Synthesis of -SiC Nanoparticles by High-Energy Mechanical Ball Milling and Their Photoluminescence Properties

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Abstract:

We succeeded in the synthesis of single-phase -SiC nanoparticles via simple and low-cost high-energy mechanical ball milling of a silicon and graphite mixture at ambient temperature. The synthesis products were characterized by X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM) and selected area electron diffraction (SAED). The results show that starting graphite and silicon mixture reacted completely into -SiC nanoparticles with an average grain size of ∼8 nm after being milled for 20 h, and the grain size gradually decreased as milling time increased from 20 to 60 h but remained basically unchanged above 60 h. The agglomeration problem of the -SiC nanoparticles synthesized by ball milling was resolved to a great extent by the introduction of 2 wt% NH4Cl to the initial Si–C mixture. Under 325 nm excitation, a stable and intensive broad emission peak at 387 nm was observed in the photoluminescence (PL) spectrum of the synthetic nanoparticles, and this emission shows an obvious blueshift of bandgap.

Keywords: BALL MILLING; GRAIN SIZE; NANOPARTICLE; PHOTOLUMINESCENCE; SIC; SYNTHESIS

Document Type: Research Article

DOI: https://doi.org/10.1166/jnn.2010.2062

Publication date: 2010-03-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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