Incorporation of Arene Metal Carbonyl Complexes within Inorganic–Organic Hybrid Mesoporous Materials by CVD Method

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Abstract:

Simple chemical vapor deposition (CVD) of M(CO)6 (M = Cr, Mo, W) onto phenylene- and biphenylene-bridged organosilica mesoporous materials (HMM-ph, HMM-biph) led to the efficient formation of C6H4M(CO)3 and (C6H4)2M(CO)3 complexes, respectively, which are directly fixed and incorporated within the framework structure of HMM-ph and HMM-biph having molecular-scale periodicity in the pore walls. FT-IR investigations revealed that thus formed C6H4M(CO)3 or (C6H4)2M(CO)3 complexes are thermally stable even under thermovacuum treatment at 473 K.

Keywords: ARENE METAL CARBONYL COMPLEX; CR; CVD; HYBRID MESOPOROUS MATERIAL; MO; W

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2010.1509

Publication date: January 1, 2010

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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