If you are experiencing problems downloading PDF or HTML fulltext, our helpdesk recommend clearing your browser cache and trying again. If you need help in clearing your cache, please click here . Still need help? Email help@ingentaconnect.com

Luminescence and Energy Transfer in Water Soluble CeF3 and CeF3:Tb3+ Nanoparticles

$113.00 plus tax (Refund Policy)

Buy Article:

Abstract:

CeF3 and CeF3:Tb3+ water soluble nanoparticles (NPs) were prepared by wet chemistry, and their structure and luminescence properties were studied systematically. The results of XRD indicate that the obtained CeF3 and CeF3:Tb3+ NPs have a hexagonal structure with the P 63/mcm space group. The average size of CeF3 NPs is about 10 nm, and that of CeF3:Tb3+ NPs is about 5.5 nm as measured from transmission electron microscope (TEM). The aqueous solution sample of CeF3 NPs has an emission peaking at 325.5 nm, which is from the 5d → 4f transition of Ce3+, and CeF3:Tb3+ NPs have a broad emission at 355.5 nm, which is from the 5d → 4f transition of Ce3+ (325.5 nm), and several sharp emissions in the visible ranges that are from the 5D47FJ transition of Tb3+. As the concentration of Tb3+ increases, the emission intensity of Ce3+ decreases gradually, while the emission intensity of Tb3+ first increases and then decreases. Our observations indicate that there is an energy transfer from Ce3+ to Tb3+ in the CeF3:Tb3+ nanoparticles, and the maximal energy transfer rate is estimated to be 93.2% at the Tb3+ concentration of 25%.

Keywords: CEF3; CEF3:TB3+; ENERGY TRANSFER; LUMINESCENCE; NANOPARTICLES; QUANTUM YIELD

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2009.1821

Publication date: November 1, 2009

More about this publication?
  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Terms & Conditions
  • ingentaconnect is not responsible for the content or availability of external websites
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more