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Single-Wall Carbon Nanotubes Chemically Modified with Cysteamine and Their Application in Polymer Solar Cells: Influence of the Chemical Modification on Device Performance

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In order to improve the dispersion of single-wall carbon nanotubes in a matrix of poly(3-hexylthiophene), this paper reports the modification of single-wall carbon nanotubes with COOH groups followed by reaction with cysteamine that introduced thiol groups along the tubes. The resulting modified single-wall carbon nanotubes were characterized by high resolution transmission electron microscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy and Raman spectroscopy. The modified carbon nanotubes were applied, in combination with poly(3-hexylthiophene), in a bulk heterojunction solar cell. After passing through a post-treatment process to obtain debundled modified single-wall carbon nanotubes, solar cells with improved performance were obtained. After the treatment sequence, both the open circuit voltage and short-circuit current increased in comparison to the non-treated modified single-wall carbon nanotubes polymer solar cells.
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Document Type: Research Article

Publication date: 01 October 2009

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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