Facile Preparation of Self-Assembled Polymer Nanotubes by Proton Beam Irradiation

Authors: Jung, Sung Ho; Jeong, Youn; Han, Won Seok; Lee, Shim Sung; Jung, Jong Hwa

Source: Journal of Nanoscience and Nanotechnology, Volume 9, Number 4, April 2009 , pp. 2777-2779(3)

Publisher: American Scientific Publishers

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Abstract:

We report the self-assembled nanotube formation and its polymerization from a sugar-based amphiphile 1 having a diacetylene functional group by proton beam irradiation. The self-assembled nanotubes were staibilized by photoreaction without the induction of any morphological changes. To further verify the polymerization of the self-assembled organic nanotube 1, we carefully measured the FT-Raman spectrum to examine changes in the diacetylene moiety of the self-assembled 1 by proton beam. After irradiation by proton beam for 30 s, the vibrational band for the diacetylene group at 1481 cm−1 (vC≡C) completely disappeared whereas a new band appeared at 1510 cm−1, which corresponds to the C=C stretching vibration region. This finding indicates that the irradiation method by proton beam is useful not only to polymerize self-assembled nanostructures with no morphology changes, but also to synthesize new functional nanomaterials.

Keywords: IRRADIATION; POLYMER NANOTUBES; PROTON BEAM; SELF-ASSEMBLY; SUGAR

Document Type: Short communication

DOI: http://dx.doi.org/10.1166/jnn.2009.dk08

Publication date: 2009-04-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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