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Self-Assembly of Bi2WO6 Square Nanoplates into Hierarchical Structures

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Abstract:

Bi2WO6 hierarchical structures constructed by a number of square nanoplates of average ∼70 nm in side length and ∼25 nm in thickness have been synthesized by a hydrothermal method at 180 °C. The single-crystal subunit nanoplates with (002) as their two-dimensional (2D) surfaces assembled orderly using both their edges and faces into free-standing films. It was found that the self-assembled growth of these hierarchical structures strongly depended on surfactant Cetyl Trimethyl Ammonium Bromide (CTAB), the amounts of the starting materials and the molar ratio of precursors (Bi3 + to WO2− 4), etc. The growth mechanism was discussed based on the comparative experimental results.

Keywords: BI2WO6; HIERARCHICAL STRUCTURES; SELF-ASSEMBLY

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2009.C195

Publication date: February 1, 2009

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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