@article {Hasegawa:2008:1533-4880:6123,
title = "Growth Window and Possible Mechanism of Millimeter-Thick Single-Walled Carbon Nanotube Forests",
journal = "Journal of Nanoscience and Nanotechnology",
parent_itemid = "infobike://asp/jnn",
publishercode ="asp",
year = "2008",
volume = "8",
number = "11",
publication date ="2008-11-01T00:00:00",
pages = "6123-6128",
itemtype = "ARTICLE",
issn = "1533-4880",
eissn = "1533-4899",
url = "https://www.ingentaconnect.com/content/asp/jnn/2008/00000008/00000011/art00077",
doi = "doi:10.1166/jnn.2008.SW17",
keyword = "COMBINATORIAL METHOD, GROWTH WINDOW, SINGLE-WALLED CARBON NANOTUBES, VERTICALLY ALIGNED NANOTUBES, GROWTH MECHANISM",
author = "Hasegawa, Kei and Noda, Suguru and Sugime, Hisashi and Kakehi, Kazunori and Maruyama, Shigeo and Yamaguchi, Yukio",
abstract = "Our group recently reproduced the water-assisted growth method, so-called "SuperGrowth," of millimeter-thick single-walled carbon nanotube (SWNT) forests by using C2H4/H2/H2O/Ar reactant gas and Fe/Al2O3 catalyst. In
this current work, a parametric study was carried out on both reaction and catalyst conditions. Results revealed that a thin Fe catalyst layer (about 0.5 nm) yielded rapid growth of SWNTs only when supported on Al2O3, and that Al2O3 support enhanced
the activity of Fe, Co, and Ni catalysts. The growth window for the rapid SWNT growth was narrow, however. Optimum amount of added H2O increased the SWNT growth rate but further addition of H2O degraded both the SWNT growth rate and quality. Addition of H2
was also essential for rapid SWNT growth, but again, further addition decreased both the SWNT growth rate and quality. Because Al2O3 catalyzes hydrocarbon reforming, Al2O3 support possibly enhances the SWNT growth rate by supplying the carbon source
to the catalyst nanoparticles. The origin of the narrow window for rapid SWNT growth is also discussed.",
}