Characterization of Electrokinetic Properties of Nanofluids

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The effects of pH value, surfactant, and electrolyte concentration on zeta potential, particle agglomeration, and thermal conductivity of nanofluids are investigated. The zeta potential of TiO2 (15 nm) nanoparticles in deionized water of different pH values was measured and the iso-electric point was found to be between 4.9 and 5.2. Addition of surfactant in the base fluid increases the zeta potential and thus increases the effective thermal conductivity of nanofluids. The results show that the higher the electrolyte concentration, the smaller the particle zeta potential, which results in increased agglomeration of particles. The enhanced thermal conductivity of TiO2/deionized water-based nanofluids was found to decrease with increasing pH value or electrolyte concentration. At 0.2 volume percentage of TiO2 nanoparticles, the decrease of thermal conductivity of nanofluids was within 2% when the pH value or electrolyte concentration was increased from 3.4 to 9 or 0.01 mM to 10 mM, respectively. The hydrodynamic diameter of agglomerated nanoparticles in base fluid was also measured and found to increase with increasing electrolyte concentration.


Document Type: Research Article


Publication date: November 1, 2008

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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