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Molecular-Level Interaction Between a Single-Walled Carbon Nanotube and Cucurbit[n]urils

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Abstract:

Interaction between single-walled carbon nanotubes (SWNTs) and a diameter-controllable supramolecule was investigated using spectroscopic and microscopic tools. Various types of cucurbit[n]uril (CB[n]), famous host molecules, were selected since their diameter can be suitably controlled and its geometric structure was well-characterized. We observed the formation of an SWNT-CB[n]complex when the SWNT was added to an acid solution of glycouril and paraformaldehyde under heating treatment and confirmed by FT-IR. The formation of the complex was visualized by field emission transmission electron microscopy. The property of SWNTs was modified by the formation of the complex, for example, enhancement in their dispersion with is promising in developing innovative nanomaterials based on SWNTs.

Keywords: CUCURBIT[N]URIL; DISPERSION; MOLECULAR INTERACTION; SINGLE-WALLED CARBON NANOTUBE

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2008.1373

Publication date: October 1, 2008

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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