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New Hole Transporting Materials Based on Di- and Tetra-Substituted Biphenyl Derivatives for Organic Light-Emitting Diodes

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This study aimed to synthesize novel hole transporting materials (HTMs) with biphenyl derivatives that are di- or tetra-substituted with naphthylphenyl amine groups and/or methoxy groups, and to examine systematically the variations of the properties of the HTMs with the number and location of the substituents. The tetranaphthylphenyl amine-substituted biphenyl-based HTMs T1N and T2N were observed to have better thermal properties than the commercial HTM NPB, with decomposition temperatures above 500 °C, and a 10 °C higher Tg. In EL devices with ITO/2-TNATA(60 nm)/HTM(15 nm)/Alq3(70 nm)/LiF(1 nm)/Al structures, the disubstituted biphenyl-based HTMs with an asymmetric molecular structure D1N and D2N were found to have inferior luminescence efficiencies when compared to NPB, which has a symmetric molecular structure. However, M1N, which is substituted with a further two methoxy groups, was found to exhibit excellent luminance and power efficiencies, 4.88 cd/A and 1.36 lm/W respectively at 100 mA/cm2, which are higher by about 147% and 127% respectively than those of NPB (3.30 cd/A and 1.07 lm/W at 100 mA/cm2), due to better charge balance.


Document Type: Research Article


Publication date: October 1, 2008

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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