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Synthesis and Photochromic Properties of Poly(4-vinylpyridine-co-styrene) with Pendant Spiroxazine Moieties

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Abstract:

An ionic polymer with pendant photochromic moieties was prepared by the reaction of poly(4-vinylpyridine-co-styrene) and 1,3,3-trimethyl-6′-bromohexyloxyspiro[2H]-indol-2,3′-[3H]-naphth[2,1-b][1,4]oxazine. The photochromic reaction in question is caused by the reversible heterolytic cleavage of the C(spiro)—O bond under UV irradiation, yielding the colored form that can return to the colorless form by ring closure under visible light irradiation or in dark. The visible range absorption of the corresponding polymer increased gradually by UV irradiation which is ascribed to the generation of the open merocyanine form from the closed spiro form. The ionic conductivity of polymer increased upon UV irradiation, which brought about the generation of zwitterions form, and subsequently decreased in dark, which brought about the generation of closed spiro form. Sufficient reversibility was found in this polymer and this response was completely synchronized with that in the absorbance changes.

Keywords: PHOTOCHROMIC BEHAVIOR; POLY(4-VINYLPYRIDINE-CO-STYRENE); POLYMER REACTION; SPIROXAZINE; UV IRRADIATION

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2008.IC75

Publication date: September 1, 2008

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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