Synthesis and Characterization of ZnO Nano-Plant-Like Electrodes
Dye-sensitized solar cells (DSSCs) have received considerable attention as a cost-effective alternative to conventional inorganic solar cells. These cells operate on a process similar to photosynthesis, the process by which green plants generate chemical energy from sunlight. A thick semiconductor nanoparticle film provides a large surface area for the adsorption of energy by light harvesting organic dye molecules which then "inject" electrons into the nanostructured semiconductor electrode. This process is accompanied by a charge transfer to the dye from an electron donor mediator supplied by an electrolyte, resetting the cycle. A significant increase in the long term stability and the efficiency of DSSCs has been realized during the last few years. However, still the current nanoparticle-based DSSCs suffer from the trap-limited diffusion transport mechanism of electrons, a slow mechanism that limits the device efficiency, especially at longer wavelengths. Recently we have developed a new version of the dye-sensitized cells in which the traditional electrode (sintered nanoparticle film) is replaced by a specially designed ZnO electrode possessing an exotic 'nanoplant-like' morphology. This advance fixes a major efficiency limiting factor in current nanoparticle-based DSSCs. The direct electrical pathway, provided by the interconnected nanoplants, provides rapid collection of carriers generated throughout the device, and significantly enhances the conversion efficiency of the system over that of sintered nanoparticle based solar cells.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
Document Type: Research Article
Publication date: 2008-08-01
More about this publication?
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Terms & Conditions
- Ingenta Connect is not responsible for the content or availability of external websites