@article {Gu:2008:1533-4880:3235,
title = "Construction of Highly Pure Nanocrystalline Heteropoly Acid Inside the Channels of Mesoporous Material with the Imprisoned Hydrolyzation Reaction of Heteropoly Acid Etherate",
journal = "Journal of Nanoscience and Nanotechnology",
parent_itemid = "infobike://asp/jnn",
publishercode ="asp",
year = "2008",
volume = "8",
number = "6",
publication date ="2008-06-01T00:00:00",
pages = "3235-3240",
itemtype = "ARTICLE",
issn = "1533-4880",
eissn = "1533-4899",
url = "https://www.ingentaconnect.com/content/asp/jnn/2008/00000008/00000006/art00064",
doi = "doi:10.1166/jnn.2008.155",
keyword = "SELF-ASSEMBLY, MESOPOROUS MATERIAL, NANOCRYSTAL, 12-TUNGSTOPHOSPHORIC ACID, HETEROPOLY ACID",
author = "Gu, Ying-Ying and Yu, Shu-Yuan and Kong, Ai-Guo and Hua, Chun-Yan and Ding, Han-Ming and Shan, Yong-Kui",
abstract = "A novel technique was developed to prepare highly pure heteropoly acid (HPA) nanocrystals inside mesoporous SBA-15 by the imprisoned reaction of HPA etherate and water, which was utilized as a main driving force for the transportation of building-blocks. The transmission electron microscopy,
X-ray diffraction, FT-IR spectrum and NMR characterizations unambiguously demonstrate that this method allows the highly pure heteropoly acid nanocrystals with intact Keggin-type structure controlled directionally self-assembly within mesopores of silica SBA-15. Such method may open up a new
entry to the highly pure multicomponent nanocrystalline particles inside the cavity of the porous materials.",
}