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Solution-Processed High-Efficiency Organic Phosphorescent Devices Utilizing a Blue Ir(III) Complex

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Abstract:

We report high-efficiency blue phosphorescence organic light-emitting devices by solution process utilizing a blue Ir(III) complex [(F2ppy)2Ir(ph-imz)CN] (F2ppy = 2′,6′ -difluoro-2-phenyl pyridine and ph-imz = N-phenyl imidazole) blended with the host mCP (N, N′-dicarbazolyl-3,5-benzene), and the inert polymers polystyrene (PS) and polymethylmethacrylate (PMMA). The effects of the dopant confinement in the PS and PMMA matrix on the device performance are studied by field emission transmission electron microscopy (FE-TEM) and atomic force microscopy (AFM). The complex shows photoluminescence peaked at 458 nm with CIE color coordinates (0.14, 0.21) in solution and (0.14, 0.18) in doped PMMA film. The PS based device showed better device performance than the PMMA based device with a maximum luminous efficiency of (L) 5.11 cd/A with CIE color coordinates (0.17, 0.29) (at 10 mA/cm2) and a maximum luminance of 9765 cd/m2.

Keywords: BLUE EMITTING IRIDIUM(III) COMPLEX; DIPOLAR CLOUD; PHOSPHORESCENT

Document Type: Research Article

DOI: http://dx.doi.org/10.1166/jnn.2008.153

Publication date: June 1, 2008

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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