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Fe(III) Containing MCM-48 Type Mesoporous Molecular Sieves with Framework Zeolite Secondary Building Units

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Abstract:

Fe(III) containing mesoporous materials (FeMMSH) with zeolite building units were first time synthesized. XRD and N2 adsorption/desorption analysis confirm the mesoporous characters similar to MCM-48. FT-IR analysis of FeMMSH showed an additional band at about 530–550 cm− 1, characteristic of double five-membered ring of zeolite (ZSM-5) secondary building unit. The Fe(III) in FeMMSH materials is present in tetrahedral, and distorted tetrahedral framework are evident from EPR and DRUV-VIS spectra.

Keywords: FEMMSH; FRAMEWORK FE(III); MESOPOROUS COMPOSITES; ZEOLITE BUILDING UNIT

Document Type: Short Communication

DOI: https://doi.org/10.1166/jnn.2008.034

Publication date: 2008-01-01

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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